Tian Yongshang,Liu Chunying,Song Xuewen,et al.Investigations of the mechanism of enhanced relaxor ferroelectricity of (K,Na)1-2x Sr x NbO3 lead-free piezoelectric ceramicsJ.Journal of Xinyang Normal University (Natural Science Edition),2026,39(3):444-450.. DOI: 10.3969/j.issn.2097-583X.2026.03.014
Citation: Tian Yongshang,Liu Chunying,Song Xuewen,et al.Investigations of the mechanism of enhanced relaxor ferroelectricity of (K,Na)1-2x Sr x NbO3 lead-free piezoelectric ceramicsJ.Journal of Xinyang Normal University (Natural Science Edition),2026,39(3):444-450.. DOI: 10.3969/j.issn.2097-583X.2026.03.014

Investigations of the mechanism of enhanced relaxor ferroelectricity of (K,Na)1-2x Sr x NbO3 lead-free piezoelectric ceramics

  • (K,Na)1-2x Sr x NbO3 (KNSN) ceramics were synthesized via solid-state sintering method, building upon the preparation of KNSN powders by the conventional solid-state reaction method. The regulatory mechanisms of Sr2+ doping on crystal structural evolution, dielectric relaxation behavior, and ferroelectric properties were systematically investigated. The phase structure, surface morphology, dielectric properties, and ferroelectric performance of the ceramics were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), precision impedance analysis, and ferroelectric testing systems, respectively. Experimental results demonstrated that, the KNSN ceramics exhibited the enhanced structural symmetry, improved densification, and strengthened dielectric relaxation with increasing Sr2+ doping content. The modulation of relaxor ferroelectric behavior in sodium potassium niobate-based lead-free piezoelectric ceramics was revealed through Sr2+ doping and clarifying the underlying mechanisms systematically, providing both theoretical and experimental support for the design of high-performance lead-free relaxor ferroelectrics.
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