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高复兴, 杨莹琴, 张玉霞, 刘雪, 戴振亚. C_6H_5CH_2C_5H_4NdCl_2·3THF的合成及催化聚合活性研究[J]. 信阳师范学院学报(自然科学版), 2004, 17(2): 189-190.
引用本文: 高复兴, 杨莹琴, 张玉霞, 刘雪, 戴振亚. C_6H_5CH_2C_5H_4NdCl_2·3THF的合成及催化聚合活性研究[J]. 信阳师范学院学报(自然科学版), 2004, 17(2): 189-190.
shu
GAO Fu-xing, YANG Ying-qin, ZHANG Yu-xia, LIU Xue, DAI Zhen-ya. Study on the synthesis and catalytic activity of C_6H_5CH_2C_5H_4NdCl_2·3THF[J]. Journal of Xinyang Normal University (Natural Science Edition), 2004, 17(2): 189-190.
Citation: GAO Fu-xing, YANG Ying-qin, ZHANG Yu-xia, LIU Xue, DAI Zhen-ya. Study on the synthesis and catalytic activity of C_6H_5CH_2C_5H_4NdCl_2·3THF[J]. Journal of Xinyang Normal University (Natural Science Edition), 2004, 17(2): 189-190.
shu

C_6H_5CH_2C_5H_4NdCl_2·3THF的合成及催化聚合活性研究

Study on the synthesis and catalytic activity of C_6H_5CH_2C_5H_4NdCl_2·3THF

    摘要
  • 摘要: 合成了苄基环戊二烯基二氯化钕配合物(C6H5CH2C5H4NdCl2·3THF).用元素分析、红外光谱分析对其结构进行了表征,该配合物与三乙基铝(AlEt3)组成的催化体系催化丁二烯聚合,单体转化率达85%.

     

    Abstract: The complex of benzylcyclopentadienyl neodymium dichloride has been synthesized and characterized by elemental analysis and IR spectra.Butadiene was polymerized by the catalyst system composed of C_6H_5CH_2C_5H_4NdCl_2·3THF and AlEt_3.The conversion percentage of butadiene can reach about 85%.

     

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