两种类型成核剂对聚丙烯结晶行为及力学性能的影响

Effects of α and β Nucleating Agent on Crystallization Behavior and Mechanical Properties of Polypro

  • 摘要: 用差示扫描量热仪和X射线衍射仪对两种类型成核剂改性的聚丙烯的结晶行为进行了表征,结果表明,两种成核剂的加入均可提高聚丙烯的结晶起始温度和结晶峰温度,并加快结晶速度.α成核剂的加入使聚丙烯结晶度增大,从而使刚性增加,但抗冲击强度有所下降;β成核剂的加入使聚丙烯中β晶含量大幅度地提高,从而使聚丙烯抗冲击强度提高,即韧性增加.

     

    Abstract: The nucleating effects of α and β nucleating agent on the crystallization behavior of polypropylene(PP) were studied by differential scanning calorimetry(DSC) and X-ray diffraction spectrum(XRD).The results shows that the addition of nucleating agents increased the onset temperature and peak temperature and improved crystallization rate of PP.With the addition of α nucleating agent,the crystallinity increased,resulted in higher rigidity and lower impact strength than those of pure PP;while with the addition...

     

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