阳离子改性淀粉的合成及其絮凝性能研究
Synthesis and Flocculating Properties of Cationic Modified Starch
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摘要: 以淀粉和二甲基二烯丙基氯化铵为主要原料,采用过硫酸铵-尿素为引发剂,合成了阳离子淀粉接枝共聚物,用红外光谱、核磁共振等对接枝物进行了结构表征.利用X-射线衍射仪观察了接枝共聚产物的微观聚集状态,并用扫描电子显微镜观察了其微观形貌.讨论了影响聚合反应的各种因素,考察了硅藻土悬浮液对产物的絮凝性能.Abstract: Cationic modified starch was synthesized with starch and diallyldimethylammonium chloride as raw material by using ammonium persulfate/carbamide initiation system.The factors on the graft copolymerization were discussed,and the flocculating properties of resultant were investigated using diatomite-containing suspension.Experimented results show that the graft polymer has good water-solubility,higher grafting level,higher cationic degree and excellent flocculation performances.The structure of the copolymer ...