铁与钒、铱、铂和钌的浮选分离研究

基金项目:

河南省教育厅自然科学研究计划项目(2006150023)

信阳师范学院校级教改项目(2009063)

Flotation Separation of Fe(Ⅲ) from V(Ⅴ),Ir(Ⅳ),Pt(Ⅳ) and Ru(Ⅲ)

1.
College of Chemistry and Chemical Engineering,Xinyang Normal University,Xinyang 464000,China
2.
College of Chemistry and Chemical Engineering,Henan University of Technology,Zhengzhou 450052,China
3.
College of Chemistry and Chemical Engineering,Xinyang Normal University,Xinyang 464000,China

摘要: 在水溶液中,铁(Ⅲ)与四丁基溴化铵和硫氰酸钾能够生成不溶于水的[Fe(SCN)6][TBAB]3三元缔合物.当加入硫酸铵后,该三元缔合物浮于水相上层形成界面清晰的液-固两相.通过浮选,Fe(Ⅲ)可以与V(Ⅴ),Ir(Ⅳ),Pt(Ⅳ)和Ru(Ⅲ)定量分离.当溶液中四丁基溴化铵和硫氰酸钾的浓度分别为0.8 mmol/L和7.0 mmol/L时,Fe(Ⅲ)的浮选率达到98.2%以上
- 铁 /
- 四丁基溴化铵 /
- 硫氰酸钾 /
- 浮选分离
Abstract: In the aqueous solutions Fe(Ⅲ) combines with tetrabutyl ammonium bromide and KSCN into a ternary ion association precipitate [Fe(SCN)6]3.In the presence of(NH4)2SO4,the precipitate was floated well on the surface of water phase to make the system to divide into liquid phase and sold phase with a distinct boundary layer.Fe(Ⅲ) could be quantitatively separated from V(Ⅴ),Ir(Ⅳ),Pt(Ⅳ) and Ru(Ⅲ) by floatation.And 98.2% floatation percentage of Fe(Ⅲ) were obtained when the concentrations of tetrabutyl ...
- ferrum /
- tetrabutyl ammonium bromide /
- KSCN /
- flotation separation

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[2]	李玉玲，沈久明，汪玲，等．钯与铱、铂、钌、铑和镓的浮选分离研究［J］．信阳师范学院学报: 自然科学版，2010，23( 1) : 131-133