聚(丙烯酸-丙烯酰胺)/膨润土/淀粉吸水性复合材料的制备及其性能
Preparation of Poly(acrylic acid-co-acrylamide)/Bentonite/Starch Super-absorbent Composite and Their
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摘要: 采用N,N-亚甲基双丙烯酰胺为交联剂,以过硫酸钾为引发剂,利用水溶液聚合法制备了聚(丙烯酸-丙烯酰胺)/膨润土/淀粉吸水性复合材料,研究了膨润土用量、引发剂、交联剂、中和度、单体质量比等因素对材料吸水性能的影响,探讨了材料的保水性和吸水速率.结果表明:当膨润土含量为丙烯酸单体的13%,引发剂含量为0.8%,交联剂含量为0.04%,中和度为85%,m(AA)/m(AM)为1时,该复合材料吸水倍数为390,其保水性能良好.Abstract: Using N,N-methylene-bis-acrylamide as crosslinker and potassium sulfate as an initator .super-absorbent composite based on bentonite and starch and poly(acrylic acid-co-acrylamide) was prepared by polymerization and cross linking reaction.The influences of the amount of bentonite,initiator agent,crosslinking agent,neutralization degree and the mass ratio of acrylic acid to acrylamide were investigated. The influence of bentonite on water absorption retentivity and water rates of composite were discussed. Th...