石墨烯/离子液体/壳聚糖/血红蛋白修饰玻碳电极检测过氧化氢

Determination of Hydrogen Peroxide by Graphene/Ionic Liquid/Chitosan Nanocomposite Modified Electrod

  • 摘要: 将石墨烯、离子液体(1-丁基-3-甲基-咪唑四氟硼酸盐)与壳聚糖结合,制备了一种新型的石墨烯-离子液体/壳聚糖纳米复合膜修饰玻碳电极.用循环伏安法研究了血红蛋白在该修饰电极上的直接电化学行为.结果表明,血红蛋白在该纳米复合膜电极上对过氧化氢具有良好的催化性能.过氧化氢的电流响应信号与其浓度在0.1~500μmol/L范围内呈线性关系,检出限为0.02μmol/L(RSN=3),为过氧化氢检测提供了一种灵敏的新方法

     

    Abstract: A modified glassy carbon electrode was fabricated based on graphene/ionic liquid/chitosan-hemeglobin composite film modification.The direct electrochemical behavior of hemoglobin at the modified electrode was investigated by cyclic voltametry.The experimental results showed that hemeglobin has good electrocatalytic activity for hydrogen peroxide on the nanocomposite modified electrode.The linear range of H2O2 was 0.1~500 μmol/L.The limit of detection was 0.02 μmol/L(RSN=3).The electrochemical se...

     

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