废旧晶体硅太阳电池中铝元素的回收技术研究

Research on the recycling technology of aluminum element from waste crystalline silicon cells

  • 摘要: 通过湿法化学回收,选择氢氧化钾(KOH)溶液浸出太阳电池中铝背场,主要研究KOH溶液的质量分数、KOH反应液与电池中铝背场摩尔比及反应条件三个关键实验参数对铝背场浸出效率的影响。针对KOH溶液质量分数(20%~70%)、固液比(1∶10~1∶60)设计了单因素变量梯度实验及交叉变量实验,并通过控制反应条件探究铝背场浸出的最佳实验参数。采用扫描电子显微镜(SEM)、X射线衍射仪(XRD)等测试表征手段,对电池铝背场浸出反应前后的形貌变化和元素组成变化进行一系列表征分析。结果表明,当KOH溶液质量分数为20%、固液比为1∶20、反应温度为70 ℃时,电池铝背场浸出效果最佳。

     

    Abstract: A wet chemical recycling approach was adopted, utilizing a potassium hydroxide (KOH) solution to leach the aluminum back-surface from solar cells. The influence of three key experimental parameters, the mass percentage of KOH solution, molar ratio of KOH to the aluminum back-surface in the cells, and reaction conditions on the leaching rate of the aluminum back-surface were investigated. A series of single-factor gradient experiments and cross-variable experiments were designed, covering KOH solution with a mass percentage ranging from 20% to 70% and solid-to-liquid ratios from 1∶10 to 1∶60, while controlling reaction conditions to determine the optimal parameters for aluminum back-surface leaching. The morphological changes and elemental composition variations of the aluminum back-surface before and after the leaching reaction were characterized using scanning electron microscopy (SEM) and X-ray diffraction (XRD). The results demonstrated that the optimal leaching effect was achieved under the following conditions: KOH solution with a mass percentage of 20%, solid-to-liquid ratio of 1∶20, and reaction temperature of 70 ℃.

     

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