江底吸泥道路底基层材料矿物组成与微观结构演化规律

Deformation characteristics and microstructural evolution patterns of riverbed silt as road subbase material

  • 摘要: 利用矿渣和燃煤灰渣对深层江底泥进行化学改性,制备了新型的道路底基层材料,通过无侧限抗压强度、矿物结构组成分析、孔隙结构、光电子能谱综合分析材料的宏矿物组成与微观结构演化规律。试验结果发现,材料28 d无侧限抗压强度可达4.0 MPa,胶凝材料最优配比质量分数为:矿渣63%、燃煤灰渣21%、激发剂14%、活化剂2%;材料矿物组成中以石英、斜方钙沸石为主;孔隙结构满足Ⅳ型等温线、H3型滞回环形式,最大吸附量40.52 cm3/g,并生成了SiO2(Al2O32.1、SiO2(Al2O30.55、CaSiO3和CaCO3等物质,从而对强度增强起到了促进作用。研究结果表明:通过改性活化可有效提升江底吸泥的化学活性,满足《城镇道路工程施工与质量验收规范》(CJJ1—2008)中道路底基层材料的最低强度限值要求,可作为道路底基层填料使用。

     

    Abstract: A solidification/stabilization approach was employed to modify riverbed silt, synthesizing it into road subbase material. The macroscopic properties and microscopic structural changes of the material were comprehensively analyzed through unconfined compressive strength tests, mineral structure composition analysis, pore structure tests and X‑ray photoelectron spectroscopy. The experimental results indicated that the material achieved an unconfined compressive strength of 4.0 MPa at 28 d. The optimal mass fraction of the binder was found to be 63% slag, 21% fly ash, 14% activator and 2% activator. The mineral composition was dominated by quartz and clinoptilolite, while the pore structure conforms to type Ⅳ isotherms, H3 hysteresis loop, with a maximum adsorption capacity of 40.52 cm3/g. Additionally, the material generated substances such as SiO2(Al2O32.1, SiO2(Al2O30.55, CaSiO3 and CaCO3, contributing to the enhancement of strength. The results showed that modification and activation can effectively enhance the chemical activity of sediment absorption at the bottom of the river, meeting the minimum strength limit requirements of road subbase materials in the “Construction and Quality Acceptance Specification for Urban Road Engineering (CJJ1—2008)”, and can be used as road subbase filler.

     

/

返回文章
返回