不同收缩口模中聚合物熔体流变行为的数值模拟
Numerical Simulation of Rheological Behaviors of Polymer Melt in Different Contraction Dies
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摘要: 挤出成型是聚合物加工工业中的一种重要成型方法。在挤出成型过程中, 聚合物熔体在收缩口附近容易出现应力集中现象, 从而导致最终制件的表面缺陷。以最终消除或减小表面缺陷为目的, 基于数值模拟的方法, 主要研究了口模的收缩外形对聚合物熔体流变行为的影响, 包括具有不同收缩长度的V-型收缩口以及喇叭型收缩口。采用Rolie-Poly模型刻画聚苯乙烯熔体在4:1收缩流中的应力-应变关系, 基于有限体积法及SIMPLE算法模拟了不同收缩长度条件下, 聚苯乙烯熔体在V-型收缩口模以及喇叭型收缩口模中的主应力差、第一法向应力差、伸展率和速率。数值结果表明: V-型收缩口、喇叭型收缩口以及收缩长度的增大, 都能有效改善收缩流中的应力集中现象, 在收缩长度相同的条件下, 喇叭型收缩口模具有更好的效果。Abstract: Extrusion molding is an important method in polymer processing industry. The stress concentration of polymer melt can occur easily at the nearby region of contraction entrance in the process of extrusion molding, which causes volume defects of the final parts. For the purpose to eliminate or reduce the volume defects, the effects of contraction profiles on the rheological behaviors of polymer melt are mainly investigated based on numerical method, including V-shaped and trumpet-shaped contraction profiles at different contraction length. Rolie-Poly model is used to describe the stress-strain relationship of polystyrene melt in 4:1 contraction flow. Numerical simulations of the principal stress difference, the first normal stress difference, stretch ratio and velocity in V-shaped and trumpet-shaped contraction flows are implemented based on finite volume method and SIMPLE algorithm. Numerical results show that the V-shaped, trumpet-shaped contraction profiles and the increase of contraction length can reduce the stress concentration, the trumpet-shaped contraction profiles have better results under the same contraction length compared with V-shaped contraction profiles.