CaO对碱激发珍珠岩轻质发泡材料性能的影响

Effect of Adding CaO on the Properties of Light Foaming Materials by Alkali-activating Perlite

  • 摘要: 以珍珠岩为主要原料、CaO为外加剂、NaOH为激发剂,制备出一种轻质高强的发泡材料。研究了不同CaO用量和焙烧温度对轻质发泡结构形貌、体积密度、抗压强度和导热系数的影响。结果表明,添加CaO可显著提高轻质材料的物理性能,Ca可促进硅铝酸盐网络的形成和基体相的硬化,还可与体系中的硅铝酸盐反应生成水化硅酸钙,起到填充三维网状结构孔隙的作用,形成疏松多孔结构。CaO的质量分数为3%、焙烧温度为650℃时,样品的性能最优,其体积密度为0.252 g/cm3,抗压强度为2.120 MPa,导热系数为0.049 W/(m·K)。

     

    Abstract: A kind of light and high-strength foaming material is prepared by using perlite as the main raw material, CaO as the admixture and NaOH as the activator. The effect of different CaO contents and sintering temperature on the morphology, bulk density, compressive strength, thermal conductivity of light foaming samples are studied. The results show that the addition of CaO can significantly improve the physical properties of light materials which are a loose and porous structure. The presence of Ca can stimulate the formation of silicate aluminate network and hardening of matrix phase, it can also react with aluminosilicate in the system to produce a large amount of hydrated calcium silicate, which can fill the pores of three-dimensional network structure. The optimum performance of the sample is obtained after sintered at 650℃ under the mass fraction of CaO is 3%, and the bulk density, compressive strength, thermal conductivity of sample are 0.252 g/cm3, 2.120 MPa and 0.049 W/(m·K), respectively.

     

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