湿地系统中重金属截留分布的季节性特征及来源研究

Study on the Seasonal Retention and Distribution Characteristics and Source of Heavy Metals in Wetland System

  • 摘要: 采用ICP-OES分析法测定了皂河人工湿地系统中植物与基质中重金属(Cu、Pb、Zn、Cr、Ni、Cd)含量,分析湿地系统中重金属污染状况随时间变化特征,通过主成分分析法和相关系数法探讨湿地中主要重金属污染物以及重金属间相关性.结果表明:(1)湿地系统在7月份对6种重金属截留率为48%~78%,4月、10月份对重金属的截留率为30%~50%.(2)植物中重金属分布量占整个湿地系统的5.14%~9.71%,基质中重金属分布量占89.11%~93.35%,湿地系统中重金属流失率在0.08%~1.78%,表明基质在湿地系统截留重金属过程中发挥主要作用.(3)主成分分析表明,表征重金属Cu、Zn污染的主成分贡献率为58.78%,表征重金属Cr的主成分贡献率为18.78%,说明Cu、Zn是湿地中的主要污染物,Cr是次于Cu、Zn的污染物.(4)相关性分析显示Ni与铵态氮和有机质在P < 0.05水平上呈现显著正相关,Cd与速效磷在P < 0.05水平上呈现显著负相关,表明Ni、Cd迁移转化过程受到湿地理化性质的影响.重金属Cu与Pb、Cu与Zn含量间在P < 0.05水平上呈现显著正相关性,说明Cu与Pb、Zn来源具有一致性,主要源于皂河两岸大小工厂排放的废水,而Ni与其他重金属间的相关性不显著,表明不同重金属具有一定的差异性来源.

     

    Abstract: Concentrations of heavy metals, including Cu, Pb, Zn, Cr, Ni, and Cd, of plants and sediments samples collected from Zaohe Wetland were determined by ICP-OES. The seasonal change characteristics of heavy metal pollution in wetland system were analyzed, and the principal component analysis and correlation analysis were performed to display the main heavy metal pollutants and the correlation between heavy metals in wetland. The results showed thatthe interception rate of six heavy metals was 48%~78% in July, and 30%~50% in April and October. In the whole wetland system, the distribution of heavy metals in plants and sediments accounted for 5.14%~9.71% and 89.11%~93.35%, respectively, and the loss rate of heavy metals in wetland system was 0.08%~1.78%, which suggested that the sediments play the main role in trapping heavy metals in wetland system. Principal component analysis showed that the contribution rate of principal component of Cu and Zn was 58.78%, while Cr was 18.78%, which indicated that Cu and Zn were the first main pollutant and Cr was the second main pollutant in the Zaohe sewage. Correlation analysis showed that there was a significant positively correlation between Ni and ammonium nitrogen and organic matter (P < 0.05), while a significant negative correlation between Cd and available phosphorus (P < 0.05), indicating that the migration and transformation of Ni and Cd were affected by the physicochemical properties of wetland. The significant positive correlation (P < 0.05) between Cu, Pb, and Zn indicated that the sources of these above heavy metals were consistent, mainly from industrial wastewater. The correlation between Ni and Pb and other heavy metals was not significant, indicating that the source of Ni and Pb was different from others heavy metals in wetlands.

     

/

返回文章
返回