Abstract: A simple one-step electrodeposition process was developed for the fabrication of the super-hydrophobic surface on the substrate of zinc. The morphology and hydrophobicity of the prepared surface were carefully studied by scanning electron microscope (SEM) and the contact angle meter. The influence of electrolysis time and concentration of the electrolyte (the ethanol solution of myristic acid) and the anticorrosive properties were studied. The results showed that the surface which possessed high water contact angle and excellent anticorrosive properties could be fabricated with the electrolysis time of 60 min and the electrolyte of 0.01 mol/L.