Abstract: Hhydration hydroquinone copper complex and hydroquinone cobalt complex were synthesized by quasi solidstate method.The content of both complexes were determined by iodimetry and EDTA titration.The composition of both complexes were characterized by elemental analysis, IR, ultraviolet absorption spectra and fluorescence spectra. The  results indicated that pure hydration hydroquinone copper complex and hydroquinone cobalt complex were obtained.Two excitation peaks and one emission peak appeared in fluorescence spectra of both complexs showed such transition metal hydroquinone complexes can be used as a potential luminescent material.