含有酰胺键的三核钴配合物的制备和表征
Preparation and Characterization of Three-core Co-complex Containing Amido-bond
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摘要: 以2,6-双(N,N’-5-乙基-1,3,4-噻二唑-2-甲酰胺)吡啶(L)为配体,通过溶剂热法合成了含有酰胺键的钴配合物.结果表明,该配合物是一个以μ3-O为中心的三核配合物,配体L则作为四齿配体同时配位于三个Co原子.配合物的热分解分两段进行,最终产物为钴的氧化物Abstract: Co-complex containing amido-bond was synthetized by solvothermal-method using 2，6-bis（N，N’-5-ethyl-1，3，4-thiadiazole-2 -formamid)pyridine(L) as ligand.The results showed that complex has three cores in the μ3-O as center and it is coordinated between three Co atoms and quadridentate ligand with L ligand through studing the structure of single crystal. Thermal decomposition process contains two stages and the final product is oxidizing material of Co
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