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于静, 燕然, 周坤洁, 马瑞甜, 曹新华, 马献涛. 铜催化下苄胺与2-甲基喹啉化合物的需氧氧化烯化反应[J]. 信阳师范学院学报(自然科学版), 2020, 33(2): 281-285. DOI: 10.3969/j.issn.1003-0972.2020.02.017
引用本文: 于静, 燕然, 周坤洁, 马瑞甜, 曹新华, 马献涛. 铜催化下苄胺与2-甲基喹啉化合物的需氧氧化烯化反应[J]. 信阳师范学院学报(自然科学版), 2020, 33(2): 281-285. DOI: 10.3969/j.issn.1003-0972.2020.02.017
shu
YU Jing, YAN Ran, ZHOU Kunjie, MA Ruitian, CAO Xinhua, MA Xiantao. Cu-Catalyzed Aerobic Oxidative Olefination of Benzyl Amines with 2-Methylquinolines[J]. Journal of Xinyang Normal University (Natural Science Edition), 2020, 33(2): 281-285. DOI: 10.3969/j.issn.1003-0972.2020.02.017
Citation: YU Jing, YAN Ran, ZHOU Kunjie, MA Ruitian, CAO Xinhua, MA Xiantao. Cu-Catalyzed Aerobic Oxidative Olefination of Benzyl Amines with 2-Methylquinolines[J]. Journal of Xinyang Normal University (Natural Science Edition), 2020, 33(2): 281-285. DOI: 10.3969/j.issn.1003-0972.2020.02.017
shu

铜催化下苄胺与2-甲基喹啉化合物的需氧氧化烯化反应

Cu-Catalyzed Aerobic Oxidative Olefination of Benzyl Amines with 2-Methylquinolines

    摘要
  • 摘要: 以廉价的铜试剂作为催化剂、以空气作为单一的氧化剂，发展了苄胺的需氧氧化新方法，用于高效、绿色制备烯基喹啉化合物，产率32%~80%.与文献方法相比，该方法催化体系简单易得、反应高效、副产物少，可以兼容MeO、NO2、F、Cl等一系列官能团.

     

    Abstract: Cu-catalyzed aerobic oxidative olefination of benzyl amines with 2-methylquinoline was developed for the green and efficient synthesis of 2-styrylquinolines with 32%~80% yields. This method requires air as the sole oxidant, cheap and easily-available CuI as the catalyst, and can tolerate various functional groups such as MeO, NO2, F, Cl etc.

     

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