郑新生, 曾繁涤, 陈光辉. 苯并噁嗪二苯醚预聚体的合成研究[J]. 信阳师范学院学报(自然科学版), 1999, 12(2): 170-174.
引用本文: 郑新生, 曾繁涤, 陈光辉. 苯并噁嗪二苯醚预聚体的合成研究[J]. 信阳师范学院学报(自然科学版), 1999, 12(2): 170-174.
Zheng Xinsheng, Zeng Fandi, Chen Guanghui. Study on the Synthesis of Benzoxazine Precursors Based on Diphenyl Ether Oligomer[J]. Journal of Xinyang Normal University (Natural Science Edition), 1999, 12(2): 170-174.
Citation: Zheng Xinsheng, Zeng Fandi, Chen Guanghui. Study on the Synthesis of Benzoxazine Precursors Based on Diphenyl Ether Oligomer[J]. Journal of Xinyang Normal University (Natural Science Edition), 1999, 12(2): 170-174.

苯并噁嗪二苯醚预聚体的合成研究

Study on the Synthesis of Benzoxazine Precursors Based on Diphenyl Ether Oligomer

  • 摘要: 以甲氧基次甲基二苯醚低聚物为基础合成了苯并口恶嗪预聚物(BODPO),用H-NMR、IR表征了该预聚物的结构,讨论了反应温度、溶剂的极性等因素对合成预聚物的结构和组成的影响。研究结果表明,BODPO预聚物的成环率在90%以上,预聚物的组成,在很大程度上依赖于反应介质或溶剂的极性。

     

    Abstract: A New type of benzoxzine precursors was systhesized based on methoxy methylene diphenyl ether oligomer.The struture of product was characterized by IR and H-NMR analysis and effects of solvent polarity,temperature on the precursor composition were investigated.The results obtained show that ring content in the composition is more than 80%, the composition of the precursors depended upon mainly the polarity of the reaction medium or solvent.

     

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